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The new R2 Clipped High Pass with backspin. Perfect to clear players on tight areas. Love it.
YouTube - PES 13 - R2 High Pass
This is a L2 Manual High Pass from Ronny with R2 aftertouch to reduce the speed of pass.
YouTube - PES 13 L2 Manual with R2
First link, very slick i'm using that too, this was actually never possible in PES afaik.
Second link, thanks for the R2 aftertouch mention, because i noticed that i was using it too for some reason, just not quite sure what it was. There's a lot of aftertouch feedback in this game after short, long and high passes, it's very subtle and/or yet outrageous at times.