Pes 2013 is the best PES not just on PS3 but ever. I had a 5 hour session last night, was only going to play a few games but I could not put the controller down. The game is a masterpiece, the passing, shooting, dribbling, dead balls, individuality, movement, keepers and tactics are all fantastic. There are things wrong like the occasional rail(even though I use super cancel A LOT sometimes you just cant get away from the rail), lack of animations, the ball not having total freedom and the PS3 can only handle a certain amount of AI routines at a time. But given how much is right with the game its easy to forget about these things.
Playing PES 2014 I can see where Konami are going and it is the right direction but the game is a shell. If they are able to take what they did with 2013 and add it to the new engine and all that it brings, along with the power of the PS4, I expect 2015 or 2016 to top 2013.